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Stephan Scheeff (@chem_synthesis) · 11/2023 · Tröts: 55 · Folger: 52
Sa 06.07.2024 14:52
Happy to share my latest #research with Prof P. Chiu (University of #HongKong) and E. Krenske (University of #Queensland):
Reductive #Aldol Reaction of cyclic enones. I personally love this work because it allows the construction of aldol products that were previously difficult to achieve. If the enolate is cyclic, an (E)-enolate is automatically formed. In most cases this leads to an anti aldol reaction, but in our case we get the syn product.
Read more: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202401485
Diastereo- and Enantioselective Construction of Stereochemical Arrays Exploiting Non-Classical Hydrogen Bonding in Enolborates M. Li, S. Scheeff, J. Chen, R.C. Johnston, A. Rizzo, E. H. Krenske, P. Chiu Chemistry - A European Journal 2024 10.1002/chem.20240148
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